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These alloys are frequently
called "fusible" alloys because they are easily
melted at a relatively low temperature compared to most
solder alloys. These alloys are made from two or more
of the following elements: Bismuth, Tin, Lead, Cadmium,
and Indium.
Each of these ingredients is used to impart specific characteristics
and properties to the alloy. The alloys can be selected
in proportions to make binary, tertiary or quarternary
alloys that melt well below their alloying elements. They
are either eutectic, which means they melt at a single
temperature (like a pure metal) or non-eutectic, which
means they have a melting range. This range is defined
as a liquidus - the temperature above which they are completely
liquid, and a solidus - the temperature below which they
are completely solid. The temperatures in between these
are defined as the "pasty range".
The characteristics of these alloys include: low vapor
pressure, good thermal conductivity, ease of handling,
high liquid fluidity, ability to be reused, and controlled
thermal dimensional properties. With this last item, an
alloy can be made with minimal solidification shrinkage.
Unlike most metals, pure bismuth expands 3.3% of volume
on changing from liquid to solid. This expansion is employed
in alloys containing bismuth to offset solidification
shrinkage. An alloy containing more than 55% of bismuth
expand and those with less than 48% contract with solidification.
Those in between alloy exhibit little change in volume.
The change in volume due to cooling is simple linear shrinkage,
but some alloys show changes in the structure of the alloy,
which permit castings made of these alloys to have dimensions,
the same or larger than those of the mold they were cast
into.
Some of these dimensional changes can continue to occur
for as long as 1000 hours after solidification. Most of
these alloys stop growing after 24 hours.
Applications
of Low Melt Alloys
|
Safety Appliances
|
Fire
sprinklers, Boiler plugs, releasing automatic fire
doors, etc. |
|
Foundry Practice
|
Making patterns, proof
casting, fusible cores, etc.. |
|
Radiation Shielding
|
Casting permanent molds
for protection. |
|
Bonding &
Sealing
|
Soldering to glass
and temperature sensitive devices. Prevents a thin
wall tube from buckling on sharp bending radii. |
|
Tube Bending
|
Prevents a thin wall
tube from buckling on sharp bending radii. |
|
Electroforming
|
To produce expendable
mandrels for complicated shapes. |
|
Figurines
|
Miniature pieces by
centrifugal rubber mold casting. |
Low Melt
Alloys
|
Constituents -Weight Percent
|
Melting Points
|
|
Alloy
|
Bismuth
|
Lead
|
Tin
|
Cadmium
|
Indium
|
Silver
|
Solidus
|
Liquidus
|
| Designation |
Bi
|
Pb
|
Sn
|
Cd
|
In
|
Ag
|
°F
|
°C
|
°F
|
°C
|
|
117
|
44.7
|
22.6
|
8.3
|
5.3
|
19.1
|
0
|
117
|
47
|
117
|
47
|
|
136
|
49
|
18
|
12
|
0
|
21
|
0
|
136
|
58
|
136
|
58
|
|
158
|
50
|
26.7
|
13.3
|
10
|
0
|
0
|
158
|
70
|
158
|
70
|
|
158-190
|
42.5
|
37.2
|
11.3
|
9
|
0
|
0
|
158
|
70
|
190
|
88
|
|
174
|
57
|
0
|
17
|
0
|
26
|
0
|
174
|
79
|
174
|
79
|
|
203
|
52.5
|
32
|
15.5
|
0
|
0
|
0
|
203
|
95
|
203
|
95
|
|
255
|
55.5
|
44.5
|
0
|
0
|
0
|
0
|
255
|
124
|
255
|
124
|
|
281
|
58
|
0
|
42
|
0
|
0
|
0
|
281
|
138
|
281
|
138
|
|
281-338
|
40
|
0
|
60
|
0
|
0
|
0
|
281
|
138
|
338
|
170
|
|
291-325
|
14
|
43
|
43
|
0
|
0
|
0
|
291
|
144
|
325
|
163
|
|
244
|
0
|
0
|
48
|
0
|
52
|
0
|
244
|
118
|
244
|
118
|
|
296
|
0
|
0
|
0
|
0
|
97
|
3
|
296
|
147
|
296
|
147
|
|
293
|
0
|
30.5
|
51.2
|
18.3
|
0
|
0
|
293
|
145
|
293
|
145
|
|
300-302
|
0
|
15
|
0
|
0
|
80
|
5
|
300
|
149
|
302
|
150
|
|
307-323
|
0
|
18
|
70
|
0
|
12
|
0
|
307
|
153
|
323
|
162
|
|
320-345
|
0
|
30
|
0
|
0
|
70
|
0
|
320
|
160
|
345
|
174
|
|
| |
|
|